PMD liner nitride films and fabrication methods for improved NMOS performance

ABSTRACT

Semiconductor devices ( 102 ) and fabrication methods ( 10 ) are provided, in which a nitride film ( 130 ) is formed over NMOS transistors to impart a tensile stress in ail or a portion of the NMOS transistor to improve carrier mobility. The nitride layer ( 130 ) is initially deposited over the transistors at low temperature with high hydrogen content to provide a moderate tensile stress in the semiconductor body prior to back-end processing. Subsequent back-end thermal processing reduces the film hydrogen content and causes an increase in the applied tensile stress.

This is a divisional application of Ser. No. 10/827,692 filed Mar. 19,2004.

FIELD OF INVENTION

The present invention relates generally to semiconductor devices with

nitride films for improved NMOS transistor performance and fabricationmethods for making the same.

BACKGROUND OF THE INVENTION

Semiconductor devices typically include MOS transistors for switching,amplification, and other functions. Current trends in the semiconductorindustry include faster switching speeds, reduced power consumption, andlower operating voltages, wherein the performance of MOS transistorsneeds to he correspondingly improved. For example, high-speedtransistors are required for modem wireless communications systems,portable computers, and other low-power, low-voltage devices, whereinMOS transistors must be adapted to operate at lower voltages using lesspower.

The carrier mobility in a MOS transistor has a significant impact onpower consumption and switching performance. The carrier mobility is ameasure of the average speed of a carrier (e.g., holes or electrons) ina given semiconductor, given by the average drift velocity of thecarrier per unit electric field. Improving the carrier mobility canimprove the switching speed of a MOS transistor, and can also facilitateoperation at lower voltages, alone or in combination with reducing thetransistor channel length and gate dielectric thickness to improvecurrent drive and switching performance.

Carrier mobility of a MOS transistor is affected by the mechanicalstress in the device channel. The carrier mobility can be improved bydepositing silicon/germanium alloy or other material layers betweenupper and lower silicon layers under compressive stress, in order toenhance hole carrier mobility in a channel region. For NMOS transistors,tensile stress in the channel material improves carrier mobility bylifting conduction band degeneracy. However, buried silicon/germaniumchannel layer devices have shortcomings, including increased alloyscattering in the channel region that degrades electron mobility, a lackof favorable conduction band offset which mitigates the enhancement ofelectron mobility, and the need for large germanium concentrations toproduce strain and thus enhanced mobility. Furthermore, such additionalalloy layers and silicon layers are costly, adding further processingsteps to the device manufacturing procedure.

Thus, there is a need for methods and apparatus by which the carriermobility and other electrical operational properties of NMOS transistordevices may be improved so as to facilitate improved switching speed andlow-power, low-voltage operation, without significantly adding to thecost or complexity of the manufacturing process.

SUMMARY OF THE INVENTION

The following presents a simplified summary in order to provide a basicunderstanding of one or more aspects of the invention. This summary isnot an extensive overview of the invention, and is neither intended toidentify key or critical elements of the invention, nor to delineate thescope thereof. Rather, the primary purpose of the summary is to presentsome concepts of the invention in a simplified form as a prelude to themore detailed description that is presented later.

The invention relates to semiconductor devices and fabrication methodstherefor, in which a liner nitride layer is formed over NMOS transistorsto provide a tensile stress in the transistor to enhance the carriermobility, thereby facilitating high-speed, low power, low voltage deviceoperation. The nitride layer can be any silicon nitride material formedover NMOS transistors, which may also function as a protective liner andas an etch-stop material during formation of openings for contacts totransistor terminals through an overlying dielectric (e.g., pre-metaldielectric or PMD), and may also be formed over PMOS transistors.

One aspect of the invention provides a method of improving NMOStransistor performance. The method comprises depositing a nitride layerover an NMOS transistor that has an initial or as-deposited hydrogencontent of about 20 atomic percent or more, and that provides a moderateinitial tensile stress in at least a portion of the NMOS transistor ofabout 400 MPa or more and about 600 MPa or less. The method furthercomprises performing at least one thermal process after depositing thenitride layer, which may include normal back-end processing, such asmetalization, sintering, or other operations in which heat is providedto a semiconductor device wafer, wherein the nitride layer comprises ahydrogen content of about 20 atomic percent or less following thethermal processing, and wherein the NMOS tensile stress is about 1 GPaor more after the thermal processing.

Another aspect of the invention provides methods for fabricating asemiconductor device, in which an NMOS transistor is formed, having anNMOS channel region in a semiconductor body. A nitride layer isdeposited over the NMOS transistor, such as after silicide contactformation, where the nitride layer has a relatively high initial (e.g.,as-deposited) hydrogen content of about 20 atomic percent or more. Thedeposited nitride layer provides a modest tensile stress in the NMOStransistor, such as about 400-600 MPa following deposition. Thermalprocessing, such as back-end metalization, sintering, etc., may then beperformed, resulting in reduction in the nitride layer hydrogen contentand increased tensile stress.

In one implementation, the final (e.g., post-back-end) stress providedto at least a portion of the NMOS region of the semiconductor body is 1GPa or more and the nitride layer hydrogen content is reduced to about15-20 atomic percent. The inventors have appreciated that the initialprovision of a meta-stable nitride with high hydrogen content over theNMOS transistors facilitates improved NMOS performance following thethermal processing associated with back-end processing, wherein thethermal processing causes a slight reduction in the nitride hydrogencontent and increases the stress effect on the NMOS channel. The endeffect is to improve the carrier mobility in the NMOS devices, whereinthe same nitride film may be concurrently formed over PMOS transistorsin a device without severe degradation. The initial nitride layer may beformed using any suitable process, such as plasma enhanced chemicalvapor deposition (PECVD) performed at relatively low depositiontemperatures (e.g., about 350 degrees C. or less in one implementation).

Another aspect of the invention provides semiconductor devicefabrication methods comprising forming at least one NMOS transistor,depositing a nitride layer over the NMOS transistor, the nitride layerproviding an initial tensile stress in at least a portion of the NMOSregion of about 400 MPa or more and about 600 MPa or less, andperforming thermal processing on the semiconductor device afterdepositing the nitride layer, wherein the nitride layer provides atensile stress in at least a portion of the NMOS region of thesemiconductor body of about 1 GPa or more following the thermalprocessing.

Yet another aspect of the invention provides a semiconductor devicecomprising an NMOS transistor with a channel having a tensile stress ofabout 200 MPa or more, and a nitride layer over the NMOS transistor thathas a hydrogen content of about 15 atomic percent or more. The nitridelayer in one implementation has a hydrogen content of about 15-20 atomicpercent, and may also be formed over PMOS transistors in the device.Still another aspect of the invention provides semiconductor devicescomprising NMOS and PMOS transistors with a nitride layer thereover,where at least a portion of the NMOS transistor region of thesemiconductor body has a tensile stress of about 1 GPa or more. Yetanother aspect of the invention provides a semiconductor devicecomprising NMOS and PMOS transistors with an overlying nitride layerthat comprises a hydrogen content of about 15 atomic percent or more.

The following description and annexed drawings set forth in detailcertain illustrative aspects and implementations of the invention. Theseare indicative of but a few of the various ways in which the principlesof the invention may be employed.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a flow diagram illustrating an exemplary method of fabricatingsemiconductor devices in accordance with one or more aspects of theinvention;

FIG. 2 is a partial side elevation view in section illustrating anexemplary semiconductor device with a nitride layer formed over NMOS andPMOS transistors in accordance with the invention; and

FIGS. 3A-3F are partial side elevation views in section illustrating theexemplary semiconductor device of FIG. 2 at various stages offabrication processing in accordance with the invention.

DETAILED DESCRIPTION OF THE INVENTION

One or more implementations of the present invention will now hedescribed with reference to the attached drawings, wherein likereference numerals are used to refer to like elements throughout, andwherein the illustrated structures are not necessarily drawn to scale.The invention provides techniques for improving the performance of NMOStransistors in semiconductor devices, in which tensile stress isprovided to the NMOS channels. The various aspects of the invention mayadvantageously be employed in order to improve NMOS carrier mobility,thereby facilitating improved switching speed and low-power, low-voltageNMOS operation, without significantly adding to the cost or complexityof the manufacturing process.

Referring initially to FIG. 1, the invention provides semiconductordevice fabrications methods and methods for improving NMOS transistorperformance using tensile stress in the transistor channel throughformation of a silicon nitride film or layer (e.g., referred tohereinafter as a nitride layer) over the transistors prior to back-endprocessing. FIG. 1 illustrates an exemplary method 10 for fabricatingsemiconductor devices in accordance with one or more aspects of theinvention. Although the method 10 is illustrated and described below asa series of acts or events, it will be appreciated that the presentinvention is not limited by the illustrated ordering of such acts orevents. For example, some acts may occur in different orders and/orconcurrently with other acts or events apart from those illustratedand/or described herein, in accordance with the invention. In addition,not ail illustrated steps may be required to implement a methodology inaccordance with the present invention. Furthermore, the methodsaccording to the present invention may be implemented in associationwith the devices and systems illustrated and described herein as well asin association with other structures not illustrated.

Beginning at 12, the method 10 comprises forming transistors at 14,including fabrication of NMOS and PMOS transistors in/on NMOS and PMOSregions of a semiconductor body, as well as performing other front-endprocessing. Any front-end processing may be performed at 14 within thescope of the invention, for example, formation of n and p wells usingdiffusion, implantation, or other suitable processing steps, as well asformation of isolation structures in field regions of a device wafer,using LOCOS, STI or any suitable isolation processing prior totransistor formation. Prospective channel regions of the semiconductorbody may be initially doped at 14 to adjust the prospective transistorwork functions, to suppress punch-through, etc. A gate dielectric isthen formed above the semiconductor body and conductive gate structuresare formed above the gate dielectric over the prospective channelregions, such as through deposition and patterning of doped polysiliconor other conductive material. Source/drain regions of the semiconductorbody are then doped using suitable dopant species for NMOS and PMOStransistors, such as through selective implantation. Silicide processingis then performed at 16 to create conductive contacts at the transistorterminals (e.g., source/drains and gates), using any suitable materials(e.g., nickel silicide, cobalt silicide, etc.).

In accordance with the present invention, a nitride layer is then formedat 18 over the NMOS and PMOS transistors. The nitride material layerformed at 18 comprises silicon and nitrogen of any suitablestoichiometry. such as Si₃N₄ or stoichiometric variations thereof (e.g.,silicon nitride). In one aspect of the Invention, the nitride comprisesa relatively high initial (e.g., as-deposited) hydrogen content of about20 atomic percent or more. In another aspect of the invention, thenitride layer formed at 18 initially provides a tensile stress of about400-600 MPa in at least a portion of the NMOS region of the substrateprior to subsequent back-end thermal processing.

In one implementation, the nitride is deposited at 18 via a plasmaenhanced chemical vapor deposition (PECVD) process using a relativelylow deposition temperature of about 350 degrees C. or less to provide ameta-stable nitride film covering the NMOS and PMOS transistors withrelatively high hydrogen content, in this example, the PECVD chamberpressure is controlled to about 3.5 Torr or more, with a silane (SiH₄)gas flow of about 150 sccm or less, and ammonia (NH₃) gas flow of about2500-3000 sccm, using high frequency RF power set at about 50 W at 13.56MHz and low frequency power set at about 10-20 W 20 W at 350 KHz. Thisexemplary PECVD process provides a meta-stable silicon nitride film(e.g., Si_(x)N_(Y), where X is approximately 3 and Y is approximately 4in one example) with high hydrogen content, with the hydrogen beingbonded about equally with silicon (e.g., Si—H bonds) and with nitrogen(e.g., N—H bonds). Moreover, this as-deposited meta-stable nitride filmimparts a moderate initial tensile stress in the NMOS regions of thesemiconductor body (e.g., about 400-600 MPa in this example). The aboveis merely one example of a suitable deposition process that may beemployed to form the nitride layers of the present invention, whereinany suitable processing conditions and techniques may be employed, andall such variant implementations are contemplated as falling within thescope of the present invention and the appended claims.

After formation of the nitride layer, back-end processing is performedat 20-24, which involves heating the device wafer. The inventors haveappreciated that this thermal processing following formation of thenitride layer at 18 causes stabilization of the nitride film thatinvolves moderate reduction in the hydrogen content thereof, as well asan increase in the tensile stress in the NMOS semiconductor bodyregions. This increased NMOS tensile stress, in turn, enhances NMOScarrier mobility and improves the NMOS transistor performance, whereinportions of the NMOS channel regions of the semiconductor body willattain a tensile stress of about 200 MPa or more following the thermalprocessing, in addition to NMOS performance enhancement, the nitridefilm deposited at 18 may also operate as a PMD liner to protect theunderlying transistors from a subsequently formed pre-metal dielectric(PMD) material, and as an etch-stop layer in forming openings forcontacts to transistor terminals through the PMD material. The inventorshave further found that the same nitride film can be formed over PMOStransistors with little adverse effects on the PMOS device performance,whereby the formation of the nitride layer at 18 does not add cost orcomplexity to the fabrication of semiconductor devices.

At 20, an initial dielectric material (e.g., PMD) is formed over thenitride layer, wherein the deposition processing used in forming the PMDmaterial heats the nitride layer. At 22, conductive contacts are formedthrough the PMD layer and through portions of the nitride layer toprovide electrical connection for the transistor terminals (e.g.,connecting to the silicided transistor gates and source/drains). Thecontact formation at 22 comprises forming openings in the PMD materialthrough suitable masking and etching processes, followed by depositionof conductive material (e.g., tungsten or other suitable materials), andsubsequent planarization (e.g., chemical mechanical polishing, etc.). Aswith the PMD deposition, the contact formation at 22 further heats thenitride film overlying the NMOS (e.g., and PMOS) transistors. One ormore metalization levels or layers are then formed at 24 to provideelectrical interconnection of the various electrical components in thedevice, wherein each metalization level includes an inter-level orinter-layer dielectric (ILD) formed over a preceding level, with viasand/or trenches formed therein and filled with conductive material(e.g., copper, etc). Other typical back-end processing may be performedat 24 before the exemplary method 10 ends at 26, including hydrogensintering and other processes that further heat the nitride PMD liner.

Referring also to FIG. 2, in accordance with another aspect of theinvention, the provision of heat to the nitride film over the NMOStransistors through the back-end or other thermal processing causes atransformation thereof to a more stable final state following thethermal processing, in the exemplary implementations illustrated anddescribed herein, the back-end thermal processing causes a release ofsome of the as-deposited hydrogen content of the nitride film, whereinthe final nitride layer comprises a hydrogen content of about 20 atomicpercent or less following the thermal processing, about 15 atomicpercent or more in one example. While not wishing to be tied to anyparticular theory, it is believed that the hydrogen is primarilyreleased from the initial N-H bonds during the post-deposition thermalprocessing. In addition to the benefit from the increased tensilestress, the PMD liner nitride layer is also believed to effectivelyserve as a hydrogen source for the NMOS (e.g., and PMOS) transistors itcovers, in this regard, the release of a portion of the initially highhydrogen content (e.g., about 3-7% hydrogen is released after the filmdeposition due to subsequent thermal processing in one example), andmigration thereof into the underlying transistors is believed topassivate interface states and modify the dopant diffusion in thetransistors, resulting in an improved device.

Further, the thermal processing results in significantly increasedtensile stress in at least a portion of the NMOS region of thesemiconductor body, to a final tensile stress about 1 GPa or more in atleast a portion of the NMOS region of the semiconductor body followingthe thermal processing, wherein the final NMOS stress in portions of theNMOS channel are 200 MPa or more. The Invention provides nitride filmsthat initially impart modest tensile stresses (e.g., 400 MPa or more andabout 600 MPa or less as-deposited), and increased final stresses of 1GPa or more following post-nitride deposition thermal processing forimproved NMOS performance, in this regard, high as-deposited filmhydrogen content and/or low deposition temperatures are believed to aidin formation of an initially meta-stable nitride film, wherein lowdeposition temperatures are believed to facilitate the initially highhydrogen content of the as-deposited film.

With respect to deposition temperature, it is noted that simplyincreasing deposition temperature is believed to provide nitride filmsthat impart higher as-deposited tensile NMOS stress. However, theinvention instead provides meta-stable nitride films that inducemoderate as-deposited tensile stress levels (e.g., 400-600 MPa in theillustrated examples). The film then undergoes property changes duringthe subsequent thermal processing, wherein the modified film imparts aneven higher tensile stress in the substrate after thermal processing. Inthis regard, it is believed that simply depositing a nitride film athigher temperatures to provide high initial (e.g., as-deposited) NMOSsemiconductor body stress does not provide the same amount ofpost-thermal processing stress which can be achieved using thetechniques of the present invention, wherein the relative instability ofthe as-deposited films of the invention facilitate the change in stress.

FIG. 2 illustrates an exemplary CMOS device 102 with NMOS and PMOStransistors and a nitride PMD liner layer or film in accordance with thepresent invention, following back-end processing, wherein a multi-levelinterconnect routing structure and the corresponding ILD material layersare omitted from FIG. 2. The device 102 comprises a silicon substratesemiconductor body 104 with a p-well 106 formed in an NMOS region and ann-well 108 formed in a PMOS region, as well as field oxide (FOX)isolation structures 110. A gate dielectric 112 is formed over thesurface of the substrate 104 in NMOS and PMOS active regions of thedevice 102 between the FOX isolation structures 110, for example, athermally grown SiO₂ oxide 112 or any other suitable dielectricmaterial, Polysilicon gate electrodes 114 are formed by deposition andpatterning over the gate dielectric 112 above NMOS and PMOS channelregions of the substrate 104, Source/drains 116 and 118 are implantedwith N and P-type dopants for the NMOS and PMOS transistors,respectively, wherein the NMOS channel region is the portion of thesubstrate 104 laterally between the NMOS source/drains 116 and beneaththe gate oxide 112. Sidewall spacers 120 are formed along the gatestructure sidewalls and silicide contacts 124 are formed at the uppersurfaces of the source drains 116, 118, and the gates 114,

In accordance with the invention, the device 102 comprises a nitridelayer 130 formed over the transistors (e.g., and over the silicide 124),where the nitride layer 130 comprises a hydrogen content of about 15atomic percent or more and about 20 atomic percent or less. In addition,at least a portion of the NMOS region in the semiconductor body 104 hasa tensile stress of about 1 GPa or more, such as about 1.0 to 1.3 GPa inone example, wherein the NMOS channel region thereof is about 200 MPa ormore. The device 102 also comprises an initial dielectric (e.g., PMD)material 132 above the nitride 130, with conductive (e.g., tungsten)contacts 134 formed therein to connect with the silicide 124 of thegates 114 and the source/drains 116, 118. The exemplary nitride layer130 in the device 102 comprises silicon nitride (e.g., Si₃N₄ orstoichiometric variations thereof), including a hydrogen content ofabout 15 to 20 atomic percent, which is believed to comprise moresilicon-bonded hydrogen than nitrogen bonded hydrogen. The nitridelayers and semiconductor devices of the invention (e.g., layer 130 inthe device 102) can be formed by any suitable methods or techniqueswithin the scope of the invention.

FIGS. 3A-3F illustrate the exemplary semiconductor device 102 undergoingfabrication processing generally according to the method 10 describedabove, in FIG. 3A, the device is shown following front-end processingincluding formation of NMOS and PMOS transistors (e.g., at 14 in themethod 10 of FIG. 1), with channel regions of the semiconductor body 104extending laterally between the respective source/drains 116, 118 andunder the gate structures 112, 114. The invention may be employed inassociation with any type of semiconductor body 104, including but notlimited to silicon substrates, SOI wafers, etc. In addition, theinvention may be employed with any NMOS (e.g., and PMOS) transistors, inthe exemplary NMOS transistor, shallow trench isolation (STI) is used.The gate is a bilayer structure including SiO₂ gate oxide material 112and doped polysilicon gate contact material 114. However, any suitablegate dielectric 112 (e.g., high-k dielectrics or otherwise) andconductive gate contact material 114 may be used (e.g., includingmetals, and multilayer structures) within the scope of the invention.The source/drains 116, 118 can be of any suitable dopant species, type,concentrations, and dimensions within the scope of the invention, suchas n-doped NMOS source drains 116 (e.g., doped with phosphorus,antimony, arsenic, etc.) and p-doped PMOS source/drains 118 (e.g., dopedwith boron, gallium, etc.).

Sidewall spacers 120 are formed in FIG. 3B along sidewalls of the gates114. The sidewall spacers 120 may be any suitable material, includingbut not limited to silicon nitride, silicon oxide, or stacks orcombinations thereof. Also in FIG. 3B, silicide processing is performed(e.g., 16 in FIG. 1) to create conductive silicide contacts 124 at thetransistor gate and source/drain terminals. Any suitable silicidematerials 124 may be employed, such as nickel or cobalt silicide.

In one example, a layer of nickel is deposited over the device 102 afterformation of the sidewall spacers 120 that overlies the gate polysilicon114 of the patterned gate stacks and also the doped source/drains 116and 118 of the substrate 104. A thermal anneal is performed to react thenickel with the gate polysilicon 114 and with the source/drain substratematerial 116, 118, thereby forming a metal silicide 124 above thetransistor terminals 114, 116, and 118 as illustrated in FIG. 3B.

In FIG., 3C, a PECVD process 128 is performed to deposit a siliconnitride layer 130 over the transistors, where the layer 130 has anas-deposited hydrogen content of about 20 atomic percent or more, andwhere the nitride 130 provides an initial tensile stress of about400-600 MPa in at least a portion of the NMOS region of thesemiconductor body 104. Any suitable nitride deposition process 128 maybe used, wherein the exemplary PECVD process 128 is performed at about350 degrees C. or less, with a deposition chamber pressure of about 3.5Torr or more, a silane (SiH₄) gas flow of about 150 sccm or less, and anammonia (NH₃) gas flow of about 2500-3000 seem, using high frequency RFpower of about 50 W at 13.56 MHz, and low frequency power of about 10-20W at 350 KHz. As discussed above, the exemplary film 130 is meta-stablewith a relatively high hydrogen content and operates to impart amoderate tensile stress in all or a portion of the NMOS region of thesubstrate 104 after the deposition process 128, such that subsequentapplication of thermal energy during back-end processing causes areduction in the hydrogen content and an increase in the applied tensilestress in the NMOS region (e.g., to about 1 GPa or more in at least aportion of the NMOS region).

The nitride layer 130 may be formed to any suitable thickness within thescope of the invention, such as about 300 Å or more, about 500 Å in oneexample, Furthermore, the inventors have found that with respect todrain current performance, thicker nitride layers 130 perform betterthan thin layers 130. Since the nitride layer 130 can also be used as anetch stop layer in the creation of contact openings in a subsequentlyformed PMD dielectric material, wherein the thickness of the layer 130may be selected according to the etch stop performance as well asaccording to the desired drain current performance, and the distancebetween the sidewall spacer structures 120 of the closet two neighboringtransistors (not shown), wherein the PMD contact etch and etch-stop etchprocesses may be adjusted to accommodate thicker nitride layers 130, inthe exemplary implementations illustrated and described herein, forexample, NMOS drain current is improved by 2-10% after back-endprocessing, depending on the thickness of the nitride film 130, withminimal changes in the fabrication process flow and minimal performancedegradation of PMOS transistors. Moreover, the invention provides ahigher final NMOS region tensile stress and better NMOS transistorperformance compared with initially depositing a more stable film thatcreates high initial stress.

In FIG. 3D, an initial dielectric (PMD) layer 132 is deposited over thenitride layer 130 via a deposition process 138. In one implementation,the PMD layer 132 comprises a phosphorous doped silicon oxide, depositedto a thickness of about 9000 Å over the nitride 130, which providesinsulation between overlying

20 and underlying conductive features, such as between the silicidecontacts 124 and later-formed conductive interconnect features insubsequent metallization layers of the device 102. The depositionprocess 138 and subsequent back-end processing steps provide thermalprocessing of the nitride layer 130, causing the as-depositedmeta-stable nitride material layer 130 to further stabilize and therebyto increase the tensile stress provided in the NMOS regions of thesemiconductor body 104.

FIG. 3E illustrates the device 102 following formation of conductivecontacts 134 to connect with the silicide 124. The contact formationinvolves further thermal processing, including etching contact openingsthrough the

30 dielectric 132, and etch-stop etching to remove portions of thenitride layer 130 at the bottom of the etched contact openings. Theopenings are then filled with conductive material 134, such as tungstenor the like, and the device 102 is then planarized through chemicalmechanical polishing (CMP) or other suitable techniques, leaving thestructure as illustrated in FIG. 3E. A multilayer or multi-levelinterconnect routing (e.g., metalization) structure is then formed abovethe PMD layer 132, a portion of which is illustrated in FIG. 3F,including a first inter-level dielectric (ILD) layer 142 with dualdamascene type via/trench openings filled with conductive (e.g., copper)features 144, as well as a similarly-constructed second ILD material 152with conductive features 154 therein, wherein further interconnectlayers or levels may be provided above the ILD 152 (not shown).

The thermal processing associated with the PMD, ILD, and other back-endprocessing causes a transformation of the nitride layer 130 to a finalstate along with a release of some of the as-deposited hydrogen content,where the final nitride layer 130 in FIG. 3F has a lower hydrogencontent (e.g., about 15-20 atomic percent in this example). Moreover,the stabilization of the nitride 130 significantly Increases the appliedtensile stress in at least a portion of the NMOS region of thesemiconductor body 104, to a final tensile stress about 1 GPa or more.The Invention thus provides nitride films 130 that initially impartmodest tensile stresses (e.g., 400-600 MPa as-deposited), and increasedfinal stresses of 1 GPa or more following post-nitride depositionthermal processing for improved NMOS performance.

Although the invention has been illustrated and described with respectto one or more implementations, alterations and/or modifications may bemade to the illustrated examples without departing from the spirit andscope of the appended claims, In particular regard to the variousfunctions performed by the above described components or structures(assemblies, devices, circuits, systems, etc), the terms (including areference to a “means”) used to describe such components are intended tocorrespond, unless otherwise indicated, to any component or structurewhich performs the specified function of the described component (e.g.,that is functionally equivalent), even though not structurallyequivalent to the disclosed structure which performs the function in theherein illustrated exemplary implementations of the invention. Inaddition, while a particular feature of the invention may have beendisclosed with respect to only one of several implementations, suchfeature may be combined with one or more other features of the otherimplementations as may be desired and advantageous for any given orparticular application. Furthermore, to the extent that the terms“Including”, “includes”, “having”, “has”, “with”, or variants thereofare used in either the detailed description and the claims, such termsare intended to be inclusive in a manner similar to the term“comprising”.

1. A semiconductor device, comprising: an NMOS transistor comprising anNMOS channel region of a semiconductor body; a PMOS transistorcomprising a PMOS channel region of the semiconductor body; and anitride layer over the NMOS and PMOS transistors, wherein the nitridelayer imparts a tensile stress in the NMOS transistor with littleadverse effect on the PMOS transistor, wherein the nitride layer has aninitial hydrogen content of 20 percent or more and a subsequent hydrogencontent in the range of 15 to 20 percent after thermal treatment andwherein the initial hydrogen content is associated with a first tensilestress in at least a portion of the NMOS region and said subsequenthydrogen content is associated with a second tensile stress in theportion of the NMOS region, the second tensile stress being 1 GPa ormore and greater than the first tensile stress.
 2. The semiconductordevice of claim 1, wherein the initial hydrogen content is present asdeposited using a deposition temperature of 350 degrees or less.
 3. Thesemiconductor device of claim 1, wherein the second tensile stress is atleast 66 percent greater than the first tensile stress.
 4. Thesemiconductor device of claim 1, further comprising: a gate silicide;and a source drain silicide, wherein the nitride layer is located overand in contact with the gate silicide and source drain silicide.
 5. Asemiconductor device, comprising: an NMOS transistor comprising an NMOSchannel region of a semiconductor body; a PMOS transistor comprising aPMOS channel region of the semiconductor body; and a nitride layer overthe NMOS transistor, wherein the nitride layer imparts a tensile stressin the NMOS, wherein the nitride layer has an initial hydrogen contentof 20 percent or more and a subsequent hydrogen content in the range of15 to 20 percent after thermal treatment and wherein the initialhydrogen content is associated with a first tensile stress in at least aportion of the NMOS region and said subsequent hydrogen content isassociated with a second tensile stress in the portion of the NMOSregion, the second tensile stress being 1 GPa or more and greater thanthe first tensile stress.
 6. The semiconductor device of claim 5,wherein the initial hydrogen content is present as deposited using adeposition temperature of 350 degrees or less.
 7. The semiconductordevice of claim 5, wherein the second tensile stress is at least 66percent greater than the first tensile stress.
 8. The semiconductordevice of claim 5, further comprising: a gate silicide; and a sourcedrain silicide, wherein the nitride layer is located over and in contactwith the gate silicide and source drain silicide.